期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 27, 页码 10430-10433出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja204603u
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资金
- UCSB
- Eli Lilly
A mild formation of transient acylnitroso intermediates using a copper chloride catalyst and 1 atm of air as the terminal oxidant is described. The mild reaction conditions enable the inter- and intramolecular acylnitroso ene reaction with a wide range of functionalized alkene partners, as well as the first asymmetric variant. Notably, this transformation provides a practical and operationally simple method for effecting allylic amidation using an environmentally benign oxidant and a readily abundant transition metal.
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