期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 25, 页码 9724-9726出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja204142n
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资金
- Pfizer Inc.
- China Scholarship Council
InI(3) and InBr(3) have been found to be effective catalysts for the pi activation of C C bonds to initiate the conversion of chiral propargylic alcohols or silyl ethers to polycyclic products in excellent yields and with high stereoselectivity. The method has been applied to the synthesis of chiral fused hexacyclic ring systems with the creation of multiple new stereocenters. The power and scope of the method are illustrated by a variety of examples.
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