期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 35, 页码 13864-13867出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja206572w
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资金
- Scripps Research Institute
- National Institutes of Health (NIGMS) [1 R01 GM084019-02]
- Amgen
- Eli Lilly
- Novartis
- A*STAR
Pd-catalyzed highly para-selective C-H arylation of monosubstituted arenes (including toluene) is developed for the first time using an F+ reagent as a bystanding oxidant. This finding provides a new retrosynthetic disconnection for para-substituted biaryl synthesis via C-H/C-H cross-coupling.
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