期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 11, 页码 3744-3747出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja110898s
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资金
- Grants-in-Aid for Scientific Research [21106002] Funding Source: KAKEN
We found that a flow microreactor system enables the generation of a configurationally unstable chiral organolithium intermediate and allows for its use in a reaction with an electrophile before it epimerizes. Based on this method, the enantioselective carbolithiation of conjugated enynes followed by the reaction with electrophiles was accomplished to obtain enantioenriched chiral allenes.
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