期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 34, 页码 13280-13283出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja205391v
关键词
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资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [20108001, 20245006, 22750030, 20036008, 20038007, 22000009]
- JST
- MICINN
- DFG [GU 517/11-1, SFB 583]
- Cluster of Excellence Engineering of Advanced Materials
- Grants-in-Aid for Scientific Research [20108002, 22750030, 20108001, 20245006] Funding Source: KAKEN
The complexation behavior of La(2)@C(80) dimetallofullerenes with organic donor molecules (D) in solution has been investigated. It has been shown that La(2)@C(80) and D form 1:1 complexes as a result of electron transfer interactions in the ground state. The equilibrium between La(2)@C(80)/D and [La(2)@C(80)]degrees(-)/[D](+) in solution is readily controlled by changing the temperature and solvent.
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