期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 35, 页码 13806-13809出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja203470y
关键词
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资金
- ARC [DP0881692]
- NCI National Facility at the ANU
- Australian Research Council [DP0881692] Funding Source: Australian Research Council
A new family of long-lived alkane sigma-complexes of the type (L-OEt)Re(CO)(2)(alkane) [alkane = cyclopentane, cyclohexane, pentane; L-OEt = cyclopentadienyltris(diethylphosphito)cobaltate(III)] has been observed using both IR and NMR spectroscopies and computationally interrogated with DFT methods. The oxygen-rich coordination spheres makes these complexes perhaps more relevant as models for intermediates in metal oxide mediated hydrocarbon transformations than other known alkane sigma-complexes.
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