期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 42, 页码 16778-16781出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2075967
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资金
- NIGMS [GM-64451]
- NSF [DBI-0619576, CHE-0923264]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0923264] Funding Source: National Science Foundation
Palladium-catalyzed allyl-ally cross-coupling was investigated with substituted prochiral allylic boronates. These reactions deliver products bearing adjacent stereocenters, and the issue of diastereocontrol is therefore paramount. Under appropriately modified conditions, this allyl allyl coupling strategy was found to apply to a range of substrates, generally occurring with high enantioselectivity (92:8 to >99:1 er) and good diastereoselection (4:1 to 14:1 dr).
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