期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 51, 页码 20728-20731出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja209980d
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资金
- National Science Council
- Ministry of Education, Taiwan
We report two new formal cycloaddition reactions between nitrosobenzenes and alkenylgold carbenoids. We obtained quinoline oxides 3 in satisfactory yields from the gold-catalyzed [3 + 3]-cycloadditions between nitrosobenzenes and alkenyldiazo esters 1. For propargyl esters 5, its resulting gold carbenes react with nitrosobenzene to give alkenylimine 8, followed by a [4 + 2]-cycloaddition with nitrosobenzene.
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