期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 32, 页码 12366-12369出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja204014s
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资金
- Natural Science Foundation of China [91027035, 20933007]
- Fundamental Research Funds for the Central Universities [WK1013002]
- Key Laboratory of Analytical Chemistry for Life Science of Nanjing University
- Shanghai Institutions of Higher Learning
Here, we report the reversible interconversion between NADH and NAD(+) at a low overpotential, which is in part mediated by ubiquinone embedded in a biomimetic membrane to mimic the initial stages of respiration. This system can be used as a platform to examine biologically relevant electroactive molecules embedded in a natural membrane environment and provide new insights into the mechanism of biological redox cycling.
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