期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 33, 页码 12980-12983出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja205186k
关键词
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资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [22105006]
- Grants-in-Aid for Scientific Research [10J09449, 22105006, 21245024] Funding Source: KAKEN
The efficient synthesis of various diborylalkenes such as 1,1-, trans-1,2-, and cyclic 1,2-diborylalkenes from alkenes and diboron was achieved for the first time. Selective preparation of di- and monoborylalkenes was also realized by the appropriate choice of reaction conditions. The reaction was found to proceed via a new mechanism of dehydrogenative borylation through a monoborylpalladium complex bearing an anionic PSiP-pincer ligand as a key intermediate, which realized the efficient borylation without sacrificial hydroboration or hydrogenation of the alkene.
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