期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 36, 页码 14252-14255出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2066219
关键词
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资金
- National Science Foundation [CHE0845063, CHE0923236]
- Amgen Inc.
- Dow Chemical Company
- Northwestern University
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0923236] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [845063] Funding Source: National Science Foundation
The development of an efficient oxidative [2,3]-sigmatropic rearrangement of allylic hydrazides, via singlet N-nitrene intermediates, is reported. The requisite allylic hydrazide precursors are readily prepared and undergo smooth sigmatropic rearrangement upon exposure to iodosobenzene. The products of this novel transformation are shown to be useful precursors to a variety of compounds.
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