期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 36, 页码 14224-14227出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja206083p
关键词
-
资金
- University of California
- Santa Barbara
- Department of Energy
- UK EPSRC [GR/S06233]
- Direct For Mathematical & Physical Scien [1040541] Funding Source: National Science Foundation
- Division Of Chemistry [1040541] Funding Source: National Science Foundation
Treatment of the U(III)-ylide adduct U-(CH2PPh3)(NR2)(3) (1, R = SiMe3) with TEMPO generates the U(V) oxo metallacycle [Ph3PCH3][U(O)(CH2SiMe2-NSiMe3)(NR2)(2)] (2) via O-atom transfer, in good yield. Oxidation of 2 with 0.85 equiv of AgOTf affords the neutral U(VI) species U(O)(CH2SiMe2NSiMe3)(NR2)(2) (3). The electronic structures of 2 and 3 are investigated by DFT analysis. Additionally, the nudeophilicity of the oxo ligands in 2 and 3 toward Me3SiI is explored.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据