期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 30, 页码 10227-10229出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1037935
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资金
- GC
- HPLC departments
- Max-Planck-Society
- DFG [SPP1179]
- Fond der Chemischen Industrie
An asymmetric catalytic epoxidation of alpha-branched, alpha,beta-unsaturated aldehydes is presented. A highly synergistic combination of a primary cinchona-based amine and a chiral phosphoric acid was found to promote the reaction with excellent enantiocontrol for alpha-monosubstituted and alpha,beta-disubstituted enals.
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