期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 28, 页码 9585-9587出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja104305s
关键词
-
资金
- Alfried Krupp von Bohlen und Halbach Foundation
A conceptually novel pyrrole synthesis is reported, efficiently merging enamines and (unactivated) alkynes under oxidative conditions. In an intermolecular Rh catalyzed process, the challenging allylic sp(3) C-H activation of the enamine substrates is followed by the cyclization with the alkyne (R-3 = CO2R). Alternatively, in some cases (R-3 = CN), the enamine can be utilized for a vinylic sp(2) C-H activation. A total of 17 examples with yields above 60% is presented, together with the results of an initial mechanistic investigation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据