期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 7, 页码 2124-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja909583s
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资金
- National Institutes of Health [GM58832]
Homogeneous asymmetric hydrogenation of unprotected benzophenone N-H imines 1a-r using 1r-benzyl-N-methyl-MonoPhos as a catalyst provides chiral amines 2a-r in 80-96% yield with enantioselectivities up to 98% ee (18 examples) for ortho-substituted substrates.
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