期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 5, 页码 1474-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja909555d
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资金
- NSF [CHE-0969157]
- UCSB
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0969157] Funding Source: National Science Foundation
Homogeneous carboamination, carboalkoxylation and carbolactonization of terminal alkenes are realized via oxidative gold catalysis, providing expedient access to various Substituted N- or O-heterocycles. Deuterium-labeling studies established the anti nature of the alkene functionalization and the indispensible role of Au(I)/Au(III) catalysis. This study constitutes the first example of catalytically converting C(sp(3))-Au bonds into C(sp(3))--C(sp(2)) bonds in a cross-coupling manner and opens new opportunities to Study gold alkene catalysis where alkylgold intermediates can be readily functionalized intermolecularly.
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