4.8 Article

Synthesis and Characterization of Teranthene: A Singlet Biradical Polycyclic Aromatic Hydrocarbon Having Kekule Structures

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 32, 页码 11021-11023

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AMER CHEMICAL SOC
DOI: 10.1021/ja1049737

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资金

  1. Mitsubishi Chemical Corporation Fund
  2. Ministry of Education, Culture, Sports, Science and Technology of Japan [2105, 18350007]
  3. PRESTO-JST
  4. CREST-JST
  5. Osaka University
  6. Belgian Government [P06-27]
  7. Grants-in-Aid for Scientific Research [18350007, 21350011, 21106014] Funding Source: KAKEN

向作者/读者索取更多资源

A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.

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