期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 29, 页码 9982-9983出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja103834b
关键词
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资金
- Humboldt Foundation
- AstraZeneca
- Alfried Krupp von Bohlen und Halbach Foundation
In the catalyzed oxidative olefination of acetanilides (oxidative-Heck coupling), Rh offers great advantages over more common Pd catalysts. Lower catalyst loadings, large functional group tolerance (in particular to halides), and higher reactivity of electron-neutral olefins (styrenes) are some of the attractive features. Most interestingly, even ethylene reacts to yield the corresponding acetanilido-styrene. Moreover, the Cu(II) oxidant can also be utilized in catalytic amounts with air serving as the terminal oxidant.
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