期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 11, 页码 3664-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja100173w
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资金
- Petroleum Research Fund [48092-G1]
A catalytic enantioselective syn-1,4-bromolactonization of conjugated (Z)-enynes was reported. Diastereomeric ratios >20:1 and up to 99% enantiomeric excesses were observed. Di-, tri-, and tetra-substituted bromoallenes were prepared together with lactone heterocycles efficiently and stereoselectively, Preliminary investigations Suggest that the chiral catalyst may serve as a bifunctional reagent by interacting with both a carboxylic acid nucleophile and NBS electrophile.
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