期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 27, 页码 9262-9264出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja103016y
关键词
-
资金
- BASF SE (Ludwigshafen, Germany)
- U.S. DOE [DE-FG02-08ER15935]
- U.S. Army [W911NF-06-1-0405]
- Japan Society for the Promotion of Sciences
A procedure for making covalently linked organometallic complexes within the pores of metal organic frameworks (MOFs) has been described. An N-heterocyclic carbene precursor containing link L0 was prepared and then constructed into a MOF-5-type structure (IRMOF-76). Attempts to produce covalently bound organometallic complexes in IRMOF-76 were unsuccessful. An alternative way of linking the first metalated link, L1, into the desired metalated MOF structure, IRMOF-77, was successful. IRMOF-76 and -77 were characterized by single-crystal X-ray studies. Demonstration of permanent porosity and successful substitution of the pyridine coligand in IRMOF-77 are also described.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据