期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 15, 页码 5334-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja9107066
关键词
-
资金
- NSF [CHE-0718171]
Reported is a macrocyclic diacetylene that assembled into columns to afford porous crystals. Heating this assembly initiated a topochemical polymerization of the preorganized diacetylene units to give covalent conjugated polydiacetylenes. These stable conjugated materials maintained permanent porosity as evidenced by their type I gas adsorption isotherms with CO2 (g). Such conjugated polymeric nanotubes could possess unusual properties for sensing and electronics.
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