期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 3, 页码 920-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja9093956
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资金
- University of Rochester
- American Chemical Society Petroleum Research Fund
The direct reductive cross-coupling of alkyl halides with aryl halides is described. The transformation is efficient (equimolar amounts of the starting materials are used), generally high-yielding (all but one between 55 and 88% yield), highly functional-group-tolerant [OH, NHBoc, NHCbz, Bpin, C(O)Me, CO2Et, and CN are all tolerated], and easy to perform (uses only benchtop-stable reagents, tolerates small amounts of water and oxygen, changes color when complete, and uses filtration workup). The reaction appears to avoid the formation of intermediate organomanganese species, and a synergistic effect was found when a mixture of two ligands was employed.
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