期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 6, 页码 1822-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja909807f
关键词
-
资金
- National NSF of China [20972102, 20732003, 20772085]
- PCSIRT [IRT0846]
An efficient methodology for the synthesis Or unsymmetrical biheteroaryl molecules has been developed via Pd(II)-catalyzed oxidative C-H/C-H cross-coupling, of heteroarenes. An inversion in reactivity and selectivity has been achieved successfully to perform the desired heterocoupling. This process allows the heterocoupling of not only electron-rich N-containing, heteroarenes (e.g., xanthines, azoles, and indolizines) but also electron-poor pyridine N-oxides with various thiophenes or furans.
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