期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 39, 页码 13669-13671出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja106436y
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资金
- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-FG02-02ER15372]
Careful control of the temperature and duration of the reaction between titanium tert-butoxide and acetic acid leads to the formation of new polyoxotitanate clusters with 14, 18, and 28 Ti atoms. They are considered intermediates in the growth of Ti/O nanoclusters of increasing size. The Ti-28 cluster is the largest crystallized to date. UV/vis spectroscopy on this cluster reveals that the optical band gap is blue-shifted with respect to a cluster containing only 17 titanium atoms indicating that the optical properties are more heavily influenced by the internal structure of the particle than its size.
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