期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 42, 页码 14748-14750出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1070575
关键词
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资金
- Ministry of Education, Science, Sports, and Culture [18GS0209]
- Korea Evaluation Institute of Industrial Technology (KEIT) [K0001346] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Surprisingly high monomer selectivity was demonstrated in competitive radical addition with two kinds of methacrylates carrying sodium and ammonium cation. Crucial is size-specific recognition by a lariat crown ether embedded close to the reactive halide in a designer template initiator. Especially, a combination with an active ruthenium catalyst led to outstanding selectivity at low temperature. This template system will open the way to unprecedented sequence-regulated polymerization.
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