期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 46, 页码 16377-16379出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja109383e
关键词
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资金
- 973 Program [2006CB932903, 2009CB939803]
- NSFC [20821061, 20925102]
- Distinguished Oversea Scholar Project
- One Hundred Talent Project
- CAS
Pd(OAc)(2)-catalyzed intermolecular C-H/C-H cross-coupling reactions between electron-deficient polyfluoroarenes and simple arenes for the synthesis of fluorinated biaryls have been developed. Deuterium-labeling experiments suggested that C-H bond cleavage of the simple arenes rather than the polyfluoroarenes is involved in the rate-limiting step.
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