期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 5, 页码 1545-1557出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja904906v
关键词
-
资金
- Chemical Sciences, Geosciences and Biosciences Division of the Office of Basic Energy Sciences, U.S. Department of Energy [DE-FG02-06ER15788, DE-SC0001011]
- UNC EFRC
The mechanism of Ce(IV) water oxidation catalyzed by [Ru(tpy)(bpm)(OH2)](2+) (tpy = 2,2':6',2 ''-terpyridine; bpm = 2,2'-bipyrimidine) and related single-site catalysts has been determined by a combination of mixing and stopped-flow experiments with spectrophotometric monitoring. The mechanism features O---O coupling by water attack on Ru-V=O3+ and three peroxidic intermediates that have been characterized by a combination of spectroscopy and DFT calculations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据