期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 38, 页码 13200-13202出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja106751t
关键词
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资金
- MICINN/FEDER [CTQ2007-61048]
- Principado de Asturias [IB 08-088]
- MICINN
- European Union (Fondo Social Europeo)
The copper(I)-catalyzed regioselective [3 + 2] cyclization of pyridines toward alkenyldiazoacetates leading to functionalized indolizine derivatives is reported. A broad range of pyridine derivatives (including quinoline and isoquinoline) is compatible with this cyclization reaction. The process represents the first successful example of metal-catalyzed cyclization of a pi-deficient heterocyclic system with alkenyldiazo compounds.
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