期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 44, 页码 15490-15492出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1066338
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资金
- Italian MiUR [PRIN 2009]
- University of Palermo
- Lord Kelvin and Adam Smith Scholarship
- EPSRC
- WestChem
- NSF
- A. P. Sloan Foundation
- EPSRC [EP/H024107/1, EP/C542819/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H024107/1, EP/C542819/1] Funding Source: researchfish
Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymmetrical appended groups, have been synthesized, identified using electrospray mass spectrometry, and isolated using an approach that allows the three AA, BB, and AB compounds to be structurally characterized. Investigation of the self-assembly of the hybrids on hydrophilic surfaces reveals the formation of nanofibres with characteristics that reflect the nature of the substitution of the POM yielding a route to the programmed assembly of anisotropic hybrid nanostructures.
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