Pore Space Partition and Charge Separation in Cage-within-Cage Indium Organic Frameworks with High CO2 Uptake

The integration of negatively charged single-metal building blocks {In(CO2)(4)} and positively charged trimeric clusters {ln(3)O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.