期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 13, 页码 4528-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja9109538
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [20350062]
- Grants-in-Aid for Scientific Research [20350062] Funding Source: KAKEN
A spin-polarized donor, BTBN, which is a dibromotetrathiafulvalene derivative containing a nitronyl nitroxide group in a cross-conjugated manner, was prepared. Upon hole injection from an electrode, the neutral microcrystals of BTBN exhibited nonlinear I-V characteristics that were interpreted in terms of the space-charge-limited conduction (SCLC) mechanism. Moreover, the resistance of BTBN decreased upon application of a magnetic field below 30 K and exhibited a giant negative magnetoresistance of (R-H - R-0)/R-0 = -76% at 2 K under 5 T. These results show that the transport of carriers in the neutral unicomponent radical crystal can be controlled by the external magnetic field. These findings are important as a basis for developing molecule-based spin electronic devices.
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