期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 17, 页码 5956-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja101671q
关键词
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资金
- NFSC [20871073, 20921001, 20373001]
- THSJZ
- Key Laboratory of Polyoxometalate Science of the Ministry of Education of China
The first polyoxometalatocyclophanes have been synthesized by the covalent linkage of a hexamolybdate cluster and bisarylimido ligands containing flexible chains. These metallamacrocycles are chiral, and some of them can undergo spontaneous resolution. The work provides a new protocol for preparing chiral polyoxometalates (POMs) and chiral metallamacrocycles from achiral building blocks by fastening both ends of a flexible chain onto an achiral POM to remove the symmetric center and mirror.
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