期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 26, 页码 8866-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja103685j
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资金
- Department of Atomic Energy, Government of India
- CSIR [NWP-23]
- CSIR, Government of India
Trithienylenevinylenes having amide end functional groups form supramolecular gels in nonpolar solvents, comprised of self-assembled nanowires. These gels exhibit the unique property of solution phase epitaxy leading to the alignment of fibers on mica surface. FP-TRMC studies revealed high charge carrier mobility for xerogels from decane-chloroform whereas films obtained from chloroform solutions showed less mobility, highlighting the role of self-assembly and gelation on the electronic properties of semiconducting molecular gelators. This study opens the window for a new class of conducting gelators which may find wide application in organic electronic devices.
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