期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 16, 页码 5580-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja101525w
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资金
- Engineering and Physical Sciences Research Council
- EPSRC
- Engineering and Physical Sciences Research Council [EP/G031649/1] Funding Source: researchfish
- EPSRC [EP/G031649/1] Funding Source: UKRI
We demonstrate the first Au(I)-mediated C-H activation of arenes. Au(I) salts undergo C-H activation with electron-poor arenes, in stark contrast to Au(III) salts, which activate electron-rich arenes. This operationally simple and highly regioselective process occurs under very mild conditions and gives access to a variety of Au(I)-arene complexes in excellent yields.
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