期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 32, 页码 11033-11035出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja105176v
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资金
- Japan Society for the Promotion of Science [21750108]
- Waseda University
- Society of Synthetic Organic Chemistry, Japan
- Grants-in-Aid for Scientific Research [21750108] Funding Source: KAKEN
The palladium-catalyzed Suzuki-Miyaura cross-coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes was achieved at room temperature. The generation of a monoborate intermediate by virtue of the adjacent B atom could result in the chemoselective coupling reaction under ambient conditions.
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