期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 43, 页码 15162-15163出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja108094m
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资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [19002008]
- Grants-in-Aid for Scientific Research [19002008] Funding Source: KAKEN
pi-Conjugated disilenes with 2-naphthyl or 2-fluorenyl groups on the silicon atoms have been synthesized as air-stable emissive red solids using the bulky 1,1,3,3,5,5,7,7-octaethyl-s-hydrindacen-4-yl (Eind) groups. The strong a pi-pi* absorptions and distinct emission at room temperature, both in solution and in the solid state, have been observed due to the substantial contribution of the 3p(pi)*(Si-Si)-2p(pi)*(carbon pi-electron system) conjugation.
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