期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 31, 页码 10686-10688出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja105161f
关键词
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资金
- NIGMS [GM-64451]
- NSF [DBI-0619576]
- LaMattina Fellowship
The Pd-catalyzed cross-coupling of allylic carbonates and allyIB(pin) is described. The regioselectivity of this reaction is sensitive to the bite angle of the ligand, with small-bite-angle ligands favoring the branched substitution product. This mode of regioselection is consistent with a reaction that operates by a 3,3' reductive elimination reaction. In the presence of appropriate chiral ligands, this reaction is rendered enantioselective and applies to both aromatic and aliphatic allylic carbonates.
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