4.8 Article

Coronene Nanophase within Coordination Spheres: Increased Solubility of C60

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 8, 页码 2544-+

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AMER CHEMICAL SOC
DOI: 10.1021/ja910836h

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  1. Global COE Program (Chemistry Innovation through Cooperation of Science and Engineering)

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A 4.6 nm-sized coordination sphere confines 24 pendant coronene molecules at its core. The confined coronene molecules are fluid, forming a liquid coronene nanodroplet that Could never exist in bulk. C(60) dissolves in this nano solvent with a high local concentration.

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