期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 45, 页码 15927-15929出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1078909
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资金
- Danish Ministry for Science, Technology, and Innovation through iNANO Center
- Danish Research Councils
- Carlsberg Foundation
- Villum Kahn Rasmussen Foundation
- Danish Center for Scientific Computing
- New Century Excellent Talents in University Program [NCET-10-0607]
- National Natural Science Foundation of China [20906081]
- ERC
- Danish National Research Foundation
In this study, through the choice of the well-known G-K biological coordination system, bioligand-alkali metal coordination has for the first time been brought onto an inert Au(111) surface. Using the interplay between high-resolution scanning tunneling microscopy and density functional theory calculations, we show that the mobile G molecules on Au(111) can effectively coordinate with the K atoms, resulting in a metallosupramolecular porous network that is stabilized by a delicate balance between hydrogen bonding and metal-organic coordination.
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