期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 40, 页码 14046-14047出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja107494h
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资金
- Deutsche Forschungsgemeinschaft [1166]
- University of Bergen
Readily accessible and easy-to-use phenyliodine(III) dichloride, PhICl2, has been established as an innovative and superior reagent for the one-electron oxidation of cerium(III) complexes, comprising amide, amidinate, and cyclopentadienyl derivatives. Its use allowed the successful synthesis and structural characterization of the first members of three new classes of chloro-functionalized (organo)cerium(IV) compounds, including the long sought-after Cp3CeCl.
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