期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 3, 页码 914-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja909038t
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资金
- Institute of Bioengineering and Nanotechnology (Biomedical Research Council, Agency for Science, Technology and Research, Singapore
The catalytic reduction of carbon dioxide to carbon monoxide Under mild conditions Using aromatic aldehydes as reductants and NHCs as organocatalysts was developed. This carbon dioxide splitting reaction provides a new method for metal-free carbon dioxide reduction and Steps forward in utilizing carbon dioxide as a renewable green source under mild conditions. On the other hand, this reaction also shows a new economical way to oxidize aromatic aldehydes under mild conditions with carbon dioxide and could be applied in pharmaceutical synthesis.
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