4.8 Article

Synthesis and Photodynamics of 9-Mesitylacridinium Ion-Modified Gold Nanoclusters

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 32, 页码 11002-11003

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AMER CHEMICAL SOC
DOI: 10.1021/ja105314x

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资金

  1. Ministry of Education, Culture, Sports, Science, and Technology, Japan [20108010, 21750146]
  2. KOSEF/MEST through WCU [R31-2008-000-10010-0]

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Photoexcitation of gold nanoclusters covalently functionalized with 9-mesityl-10-methylacridinium ion (Mes-Acr(+)) resulted in the formation of the electron-transfer state (Mes(center dot+)-Acr(center dot)), which forms a pi-dimer radical cation with the neighboring Mes-Acr(+) via an intramolecular pi-pi a interaction.

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