期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 14, 页码 5176-5178出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja910184j
关键词
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资金
- Swiss National Science Foundation
- EPSRC
- GSK
A fully diastereoselective total synthesis of the lycorenine-type Amaryllidaceae alkaloid (+/-)-clivonine (19) is reported via a route that employs for the first time a biomimetic ring-switch from a lycorine-type progenitor, thereby corroborating experimentally the biogenetic hypothesis first expounded for these compounds by Barton in 1960.
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