期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 35, 页码 12226-12227出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja106116v
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资金
- MEST, Korea [20100001710]
- RIPS
An asymmetric total synthesis of trilobacin (1), an annonaceous acetogenin with potent anticancer activities, was accomplished wherein the construction of its etythro-bis(2,2')-tetrahydrofuran core 2 featured a novel organoselenium-mediated oxonium ion formation/SiO2-promoted fragmentation of alpha,alpha'-cis-oxocene 3.
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