期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 21, 页码 7248-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1013739
关键词
-
资金
- University of California, Santa Barbara
- Department of Energy
Addition of Me(3)Sil to UO(2)((Ar)acnac)(2) (ArNC(Ph)CHC(Ph)O, Ar = 3,5-(t)Bu(2)C(6)H(3)) (1) results in the formation of U(OSiMe(3))(2)I(2)((Ar)acnac) (2) in moderate yield. Also formed in the reaction are I(2) and ArNC(Ph)=CHC(Ph)OSiMe(3), the product of [(Ar)acnac](-) abstraction by Me(3)Si(+). In contrast, reaction of 1 with Me(3)SiX (X = Cl, OTf) only results in the formation of UO(2)(OTf)(2)((Ar)acnacH)(2)(Et(2)O) (3) and UO(2)Cl(2)((Ar)acnacH)(2) (4), respectively.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据