期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 4, 页码 1328-1333出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja907220f
关键词
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资金
- National Natural Science Foundation of China [20821003, 20873160, 20821120291]
- National Basic Research Program of China [2010CB934100]
- Chinese Academy of Sciences
- Deutsche Forschungsgemeinschaft
- SFB 624
- NSF [CHE-0820955]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0820955] Funding Source: National Science Foundation
The synthesis and scanning tunneling microscopy (STM) investigations of shape-persistent arylene-ethynylene-butadiynylene macrocycles along with their codeposites with metallacycles are reported. 2D ordered arrays of macrocycles and macrocycle/metallacycle architectures (1:1) have been obtained on HOPG by self-assembly under ambient conditions. It is found that the ordered macrocycle array acts as a template for the deposition of the adlayer molecules. For each underlying macrocycle, one metallacycle has been detected. The unit-cell data of both, the macrocycles; and their codeposites, show that the structural information of the macrocycle layer is perfectly transformed to the guest molecules. A rather unexpected observation is that the present compound could not be coadsorbed with C-60, indicating that only a minor change in the structure of the macrocycle has a dramatic effect on the ability of the monolayer to bind additional guest molecules.
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