期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 8, 页码 2546-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja9108566
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资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [17GS0207, 20036024]
- Korea Institute of Science and Technology
- Grants-in-Aid for Scientific Research [21750042] Funding Source: KAKEN
The reactivity of a bulky, diaryl-substituted disilyne, Ar-Si Si-Ar, was examined for the first time. Reaction of the disilyne with ethylene yielded an ethylene-bridged bis(silacyclopropane), which is interpreted as a Further reaction product of the initially formed 1,2-disilacyclobutene species with ethylene. A cyclohexane fused with a 1,2-disilacyclobutene was obtained in the reaction with cyclohexene. In the reaction with 2,3-dimethyl-1,3-butadiene, a tricyclo derivative was isolated from the complex product mixture.
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