期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 51, 页码 18054-18056出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja109677n
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资金
- Danish National Research Foundation
Generation-4 polyamidoamine (PAMAM) dendrimers were surface-functionalized with azides or alkynes and conjugated to one DNA strand. DNA-controlled self-assembly of alternating azide and alkyne dendrimers on a DNA template enabled the coupling of the dendrimers by the azide-alkyne click reaction to form covalently coupled dimers, trimers, and tetramers. Polymerization of the DNA-dendrimer conjugates was also demonstrated, as well as assembly in a circular structure on DNA origami and imaging by atomic force microscopy.
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