4.8 Article

Pd(OAc)2 Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 13, 页码 4506-+

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AMER CHEMICAL SOC
DOI: 10.1021/ja908434e

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  1. NSF of China [20902100, 20852003, 20832008]
  2. Shanghai Rising-Star Program [09QA1406900]
  3. SIOC

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An efficient, Pd(OAc)(2) catalyzed method for direct olefination of highly electron-deficient perfluoroarenes was developed. The reaction scope includes a series of activated and nonactivated alkenes in moderate to high yields with moderate to high regio- and stereoselectivities.

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