期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 11, 页码 3737-3750出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja907584x
关键词
-
资金
- NIH [GM-38401, GM-77387]
- Dow Corning Corporation
We report detailed studies on two S = 2 electronic states of high-spin iron(II) porphyrinates. These two states are exemplified by the five-coordinate derivatives with either neutral imidazole or anionic imidazolate as the axial ligand. The application of several physical methods all demonstrate distinctive differences between the two states. These include characteristic molecular structure differences, Mossbauer spectra, magnetic circular dichroism spectroscopy, and integer-spin EPR spectral distinctions. These distinctions are supported by DFT calculations. The two states are characterized by very different spatial properties of the doubly occupied orbital of the high-spin that are consonant with the physical properties.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据